As far as I can tell only the chapters 10 & 11 on Simulation are truly and utterly obsolete. The old particles do not exist anymore and I guess (but I'm not sure) the Rigid Body Simulation (chapter 12) in XSI 5 still was ODE-based, whereas later version switched to being PhysX based. But you still can work with ODE in Softimage AFAIK, so that shouldn't even be a problem...
There might be some other stuff that has changed/been improved upon, but I think that can be considered "minor". My personal experience is that while stuff changes, most of it has stayed intact, even if newer/better tools have become available additionally...
And you're better off with an old, good tutorial, than no good tutorial at all...
